Water-soluble SNS cationic palladium(II) complexes and theirSuzuki–Miyaura cross-coupling reactions in aqueous medium

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dc.contributor.authorFiebor, Alphonse
dc.contributor.authorTia, Richard
dc.contributor.authorMakhubela, Banothile C. E.
dc.contributor.authorKinfe, Henok H.
dc.date.accessioned2020-07-08T14:22:02Z
dc.date.accessioned2023-04-19T02:07:17Z
dc.date.available2020-07-08T14:22:02Z
dc.date.available2023-04-19T02:07:17Z
dc.date.issued2018-07-23
dc.descriptionAn article published by Beilstein-Instituten_US
dc.description.abstractUnlike their SCS analogues, SNS pincer complexes are poorly studied for their use in coupling reactions. Accordingly, a series ofwater soluble cationic Pd(II) SNS pincer complexes have been successfully synthesised and investigated in detail for their catalyticactivity in Suzuki–Miyaura coupling reactions. By using only 0.5 mol % loading of the complexes, the coupling of inactivated arylbromides and activated aryl chlorides with various boronic acids in water was achieved in excellent yields and the catalysts werefound to be reusable for three cycles without a significant loss of activity. The investigation of the mechanism of the reactionrevealed that a Pd(II) to Pd(IV) route is the more likely pathway which was further supported by computational studies.en_US
dc.description.sponsorshipKNUSTen_US
dc.identifier.urihttps://ir.knust.edu.gh/handle/123456789/12662
dc.language.isoenen_US
dc.publisherBeilstein-Instituten_US
dc.subjectcationic palladium(II) complexesen_US
dc.subjectPd(II)/Pd(IV) complexesen_US
dc.subjectSNS pincercomplexesen_US
dc.subjectSuzuki–Miyauraen_US
dc.titleWater-soluble SNS cationic palladium(II) complexes and theirSuzuki–Miyaura cross-coupling reactions in aqueous mediumen_US
dc.typeArticleen_US
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