Browsing by Author "Peprah, Blissbern Owusu"

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    Enhancing Biogas Recovery from Anaerobic Co-digestion of Human Excreta and Food Waste using Response Surface Method and Biochar Additives
    (KNUST, 2023-09) Peprah, Blissbern Owusu
    Ghana shares similar challenges with other developing nations regarding waste management and access to clean energy. Fortunately,these two challenges are connected. A better waste management strategy would involve converting the organic waste fractions into biogas. Nevertheless, a thorough study of the physico-chemical characteristics of the feed stocks used in the anaerobic digestion process is essential to maximize the energy potential. Consequently, the first phase of this study examined the physical chemical properties of some selected feedstocks, namely, human excrement (HE), food leftovers (FLO), kitchen residues (KR), and cowdung (CD) of Ghanaian origin using APHA standards and equipment. Results of volatile-to-total solid ratios (VS/TS), 0.97±0.001, 0.89±0.001, and 0.85±0.001 for HE, FLO,KR and CD, respectively, showed that all feed stocks had high biodegradable content. though thecarbon-to-nitrogen(C/N)ratiosforFLO(22.14±0.26),KR(23.34±0.25) and CD(26.19±0.47)werewithintheoptimalrange,thatofHE(8.29±0.09)was significantly low.Withameanalkalinityof1219.67±1.53,630.00±0.58,590.00± 2.08 and15,730.00±6.00mgCaCO3 eq./L forHE,FLO,KRandCDrespectively, it wasobservedthatonlyCDhastheoptimalalkalinityvalueforanaerobicdiges- tion. Thisbroughtintoperspectivetheneedforco-digestion.Thesecondphaseof the study,therefore,soughttoprovethehypothesisthatanaerobicco-digestionofHE, FLO andKRcouldgeneratemorebiogaswhileremainingstableifpositivesynergis- tic effectsareachieved.Arandomizedternarymixturedesignandaresponsesurface approach wereusedtoascertaintherelationshipbetweensubstratemixture,biogas yield, methaneyield,andsynergy.ThefindingsrevealedthatR9(78.8%HE:11.8% FLO:9.4 %KR)hadthehighestmethaneyieldof764.79mLCH4/gVS andasyner- gistic indexof3.26.Additionally,the3Dresponsesurfaceplotsshowedimportant and sharedinteractionsbetweenHE,FLO,andKRwherebythepredictedresponses increased withincreasingHEandKRfractionsanddecreasedwithincreasingFLO fractions inthesubstratemixtures.Inthethirdphaseofthestudy,theexperimental cumulativemethaneyieldfromtheoptimumanaerobicco-digestionratio,R9,wasfit- ted tofivekineticmodelsandtheconemodelhadthebestfitrecordingan R2 value of 0.9909.Finally,theeffectsofcoconutshell(CCN)andpalmkernelshell(PKN) biochar dosages(3g,6gand10g)ontheanaerobicco-digestionofHE,FLOand KR wereinvestigatedusingbatchmesophilicexperiments.Theresultsshoweddif- ferences inthepeakoccurrencetimesandmethaneyieldswiththebiochar-amended treatments peakingearlierthanthecontroltreatment.Further,methaneyield(456.25 mLCH4/gVS) increasedwhen3gofCCNbiocharwasused,depictinga23.31%in- crease comparedtothecontrol(SM=370.03mLCH4/gVS). However,toohighCCN biochar dosagesof6gand10grestrictedmethaneproductionduetoapotentialstress on theanaerobicdigestionprocessbroughtonbytheaccumulationof H2 competitors of methanogensthatmighthaveclonedontoexcessbiocharandweakeneditsDIET benefit formethanogenesis.Furthermore,themethaneyieldwas368.69mLCH4/gVS, similar tothatofthecontrol(SM)when3gofPKNshellbiocharwasaddedtothe mixture offeedstocks.Nonetheless,methaneyieldincreasedby10.83%whenthe dosage ofPKNshellbiocharusedwasincreasedto6g.Conversely,PKN10gobserved a decreaseincumulativemethaneyield.Theobservedresultsindicatethatmicrobial activityandkineticscouldpossiblyberestrictedbyexcessivedosageofbiochar.This could beattributedtothepossibleadsorptionofvolatilefattyacids(VFAs)sincethe adsorption mechanismofbiocharisnotselective.Hence,higheramountsofadded biochar maynotnecessarilycorrespondtohigherdigestionefficiency.